Diesel Oxidation Catalysts
Typical Conversion Efficiencies
NOx |
CO |
HC |
Aldehydes (odor causing) |
PM10 |
Nil |
70-95% |
70-90% |
70-90% |
10-40% |
* Less than 50 ppm sulphur in diesel fuel is required for PM 10 conversion
Reactions
Carbon Monoxide |
CO + ½O2 → CO2 |
(1) |
Gas Phase Hydrocarbons |
CmHn + (m + n/4) O2 → m CO + n/2 H2O |
(2) |
Liquid Phase Hydrocarbons (SOF) |
CmHn + (m + n/4) O2 → m CO2 + n/2 H2O |
(3) |
Aldehydes, Ketones, etc. |
CmHnO + (m + n/4 – 0.5) O2 → m CO2 + n/2 H2O |
(4) |
The diesel oxidation catalyst (DOC) is effective for the control of carbon monoxide (CO), hydrocarbons (HC), odor causing compounds and the soluble organic fraction (SOF) of particulate matter (PM10).
Oxidation Catalysts
Typical Conversion Efficiencies
NOx |
CO |
NMHC |
VOC |
CH20 |
HAPs |
Nil |
70-99% |
40-90% |
60-99% |
60-99% |
60%-99% |
Reactions
Carbon Monoxide |
CO + ½ O2 → CO2 |
(1) |
Hydrocarbons |
CmHn + (m + n/4) O2 → m CO2 + n/2 H2O |
(2) |
Aldehydes, Ketones, etc. |
CmHnO + (m + n/4 – 0.5) O2 → m CO2 + n/2 H2O |
(3) |
Hydrogen |
H2 + ½ O2 → H2O |
(4) |
Three-Way Catalysts
Typical Conversion Efficiencies
NOx |
CO |
HC |
CH20 |
HAPs |
90-99% |
90-99% |
50-90% |
80-95% |
80-95% |
Reactions
Oxidation reactions with O 2: |
CO + ½ O2 → CO2
HC + ½ O2 → CO2 + H2O
HC + ½ O2 → CO + H2O
H2 + ½ O2 → H2O
|
Oxidation/reduction reactions with NO: |
CO + NO → ½ N2 + CO2
HC + NO → N2+ H2O + CO2
HC + NO → N2 + H2O + CO
H2 + NO → ½ N2 + H2O
H2 + 2 NO → N2O + H2O
5/2 H2 + NO → NH3 + H2O
2 NO + 2 NH3 + ½ O2 → 2N2 + 3 H2O
|
Water-gas shift reaction: |
CO + H2O → CO2 + H 2
|
Reforming reactions: |
HC + H2O → CO2 + H2
HC + H2O → CO + H2
|
Flow-Through Diesel Particulate Filter
Typical Conversion Efficiencies
DCL Diesel Particulate Filter Type |
Particulate matter measured by particle count* |
Particulate matter(PM10) measured by mass** |
CO |
HC |
NOx |
MINE-X pDPF® Diesel Particulate Filter |
>99% |
Up to 60% |
95% |
85% |
NO2/NO ratio may increase |
* Requires diesel fuel with sulphur content less than 500ppm
** Works best with sulphur content less than 15ppm (USLD fuel)
Diesel Particulate Filters
DCL's DPFs are highly effective in the elimination of particulate matter (PM10) or soot from diesel exhaust. DCL offers a variety of filter coatings and designs, depending on the engine application and duty cycle. Contact a DCL professional for assistance with choosing the right filter for your application.
Typical Conversion Efficiencies
DCL Filter Type |
Particulate matter measured by particle count* |
Particulate matter(PM10) measured by mass** |
CO |
HC |
NOx |
MINE-X SOOTFILTER® |
>99% |
> 85% |
90% |
60-80% |
NO2/NO ratio may increase |
MINE-X SOOTFILTER® BM |
>99% |
> 85% |
- |
- |
no change in NO2/NOx ratio |
* ultra-fine and fine particles (diameter 10 - 500 nm)
** Requires less than 15 ppm sulfur in fuel for best performance.